GaAsPN core–shell nanowire-based red microLEDs overcoming the efficiency cliff problem
Authors:
- Kristina NovikovaKNKristina Novikova
- Alexander GoltaevAGAlexander Goltaev
- Alina MaksimovaAMAlina Maksimova
- Andrey K. KaveevAKAndrey K. Kaveev
- Vladimir V. FedorovVFVladimir V. Fedorov
- Demid A. KirilenkoDKDemid A. Kirilenko
- Viktoria VolosatovaVVViktoria Volosatova
- Fedor I. ZubovFZFedor I. Zubov
- Eduard MoiseevEMEduard Moiseev
- Alexander PavlovAPAlexander Pavlov
- Aliaksandr SmirnovASAliaksandr Smirnov
- Vladislav SharovVSVladislav Sharov
- 22 September 2025
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry C
- Vol. 13 (45) , 22741-22749
Abstract
Light emitting diodes (LEDs) based on III-V semiconductors are in a great demand for many appli cations and tend to be miniaturized. However, with downscaling of planar LEDs, the surface states on the structure sidewalls, acting as nonradiative recombination centers, begin to play a significant role and deteriorate the device performance. The transition from planar to nanowire-based geometry helps to overcome this limitation. Here, we introduce a bottom-up microLED structure based on epitaxial GaP/GaAsPN/GaP nanowire arrays grown on low-cost Si(111) wafers. The active region demonstrates bright photoluminescence in the red spectral region while the radial p-i-n structure allows for electrical pumping. The opto-electrical characteristics and performance of the suggested microLEDs remain with the miniaturization of devices down to microscale equivalent lateral size. Moreover, we didn’t observe an efficiency cliff even for current density exceeding 300 A/cm2. The proposed architecture paves the way to a new generation of nanowire-based microLEDs.Keywords
Funding Information
- Ministry of Science and Higher Education of the Russian Federation (FSEG-2024-0017, FSRM-2023-0007)
- Saint Petersburg State University (95408592)
This publication has 48 references indexed in Scilit:
- Recent progresses on InGaN red micro-LEDs for displayProgress in Quantum Electronics, 2025
- Selective area epitaxy of gallium phosphide-based nanostructures on microsphere lithography-patterned Si wafers for visible light optoelectronicsMaterials Research Bulletin, 2024
- Highly-doped MBE-grown GaP nanowires: Synthesis, electrical study and modelingScripta Materialia, 2024
- True‐Red InGaN Light‐Emitting Diodes for Display ApplicationsPhysica Status Solidi (RRL) – Rapid Research Letters, 2024
- III–V Thin Films for Flexible, Cost-Effective, and Emerging Applications in Optoelectronics and PhotonicsAccounts of Materials Research, 2023
- Dual-functional light-emitting and photo-detecting GaAsPN heterostructures on siliconMaterials Science in Semiconductor Processing, 2023
- Elastic Gallium Phosphide Nanowire Optical Waveguides—Versatile Subwavelength Platform for Integrated PhotonicsSmall, 2023
- Large-Scale Synthesis of Highly Uniform Silicon Nanowire Arrays Using Metal-Assisted Chemical EtchingChemistry of Materials, 2020
- GaPAsN-based light-emitting diode on siliconOptics & Laser Technology, 2020
- Semiconductor nanowires: to grow or not to grow?Materials Today Nano, 2020