Cs 3 Bi 2 I 9 nanodiscs with phase and Bi( iii ) state stability under reductive potential or illumination for H 2 generation from diluted aqueous HI

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Abstract
Cs 3 Bi 2 I 9 nanodiscs show unprecedented lattice stability through the retention of a Bi( iii ) state in aqueous diluted hydroiodic acid after 8 h of illumination yielding 22.5 μmol h −1 H 2 for ≥20 h under cathodic bias generating 11.7 H 2 per s turnover frequency.
Funding Information
  • Council of Scientific and Industrial Research, India (No-09/921(0180)/2017-EMR-I)
  • Department of Science and Technology, Ministry of Science and Technology, India
  • University Grants Commission
  • Anusandhan National Research Foundation (CRG/2020/000084)
  • Anusandhan National Research Foundation (STR/2021/000001)

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