Chirally Sensitive Electron-Induced Molecular Breakup and the Vester-Ulbricht Hypothesis
- 12 September 2014
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 113 (11) , 118103
Abstract
We have studied dissociative electron attachment in sub-eV collisions between longitudinally polarized electrons and chiral bromocamphor molecules. For a given target enantiomer, the dissociative Br anion production depends on the helicity of the incident electrons, with an asymmetry that depends on the electron energy and is of order . The existence of chiral sensitivity in a well-defined molecular breakup reaction demonstrates the viability of the Vester-Ulbrict hypothesis, namely, that the longitudinal polarization of cosmic beta radiation was responsible for the origins of biological homochirality.
Keywords
Funding Information
- National Science Foundation (PHY-1206067)
- National Aeronautics and Space Administration (NASA)
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