Short-time statistics of extinction and blowup in reaction kinetics
- 4 May 2026
- journal article
- Published by American Physical Society (APS) in Physical Review E
- Vol. 113 (5) , 054101
Abstract
We study the statistics of extinction and blowup times in well-mixed systems of stochastically reacting particles. We focus on the short-time tail, T→0, of the extinction- or blowup-time distribution P_{m}(T), where m is the number of particles at t=0. This tail often exhibits an essential singularity at T=0, and we show that the singularity is captured by a time-dependent WKB (Wentzel-Kramers-Brillouin) approximation applied directly to the master equation. This approximation, however, leaves undetermined a large pre-exponential factor. We show how to calculate this factor by applying a leading- and a subleading-order WKB approximation to the Laplace-transformed backward master equation. Accurate asymptotic results can be obtained when this WKB solution can be matched to another approximate solution (the "inner" solution), valid for not too large m. We demonstrate and verify this method on three examples of reactions which are also solvable without approximations.Keywords
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Funding Information
- Israel Science Foundation (1579/25)
This publication has 14 references indexed in Scilit:
- Fluctuations of blowup time in a simple model of a super-Malthusian catastropheJournal of Statistical Mechanics: Theory and Experiment, 2025
- WKB theory of large deviations in stochastic populationsJournal of Physics A: Mathematical and Theoretical, 2017
- Stochastic Population and Epidemic Models2015
- A Kinetic View of Statistical Physics2010
- Stochastic models of population extinctionTrends in Ecology & Evolution, 2010
- Handbook of Stochastic Methods2004
- A Guide to First-Passage Processes2001
- Finite-time singularity in the dynamics of the world population, economic and financial indicesPhysica A: Statistical Mechanics and its Applications, 2001
- Kinetics of Small Systems. IIThe Journal of Chemical Physics, 1964
- Statistical Fluctuations in Autocatalytic ReactionsThe Journal of Chemical Physics, 1940