Asymmetric Hydrogenation of Enol Phosphinates by Iridium Catalysts Having N,P Ligands
- 28 March 2007
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 9 (9) , 1659-1661
Abstract
Enol phosphinates, which are structural analogues of enol acetates, have for the first time been employed as substrates for Ir-catalyzed asymmetric hydrogenation. A number of enol phosphinates have been synthesized and reduced successfully with up to and above 99% ee.Keywords
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