Synthesis and Characterization of Novel Grid Coordination Polymer Networks Generated from Unsymmetrically Bridging Ligands
Authors:
- 7 August 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 42 (18) , 5459-5461
Abstract
Self-assembly between simple unsymmetrical ligands, such as 1-(3-pyridyl)-2-(4-pyridyl)ethene (L 1) and 1-methyl-1‘-(3-pyridyl)-2-(4-pyrimidyl)ethene (L 2), and Co(NCS)2 affords the unprecedented two-dimensional grid coordination polymers [Co(L 1)2(NCS)2]∞ (1) and [Co(L 2)2(NCS)2]∞ (2), respectively, with novel topological features which cannot be achieved using symmetrically bridging ligands.Keywords
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