An unprecedented “strongly” self-catenated MOF containing inclined catenated honeycomb-like units
- 7 January 2016
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 45 (6) , 2426-2429
Abstract
A 3D MOF {[Co(bibp)(1,4-chdc)]·2H2O}n (1) (bibp = 4,4′-bis(1-imidazolyl)biphenyl, 1,4-H2chdc = 1,4-cyclohexanedicarboxylic acid) was hydrothermally synthesized. This framework buries an unprecedented self-catenated net with the highest topological density among the 4-coordinated nets. The photo-catalytic and electrochemical activities were investigated.Keywords
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