Design of Polymethine Dyes with Large Third-Order Optical Nonlinearities and Loss Figures of Merit
Top Cited Papers
- 19 March 2010
- journal article
- research article
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 327 (5972) , 1485-1488
Abstract
Dying by Design: To make optical-switching applications a reality, losses from scattering and other absorption processes have to be minimized. Hales et al. (p. 1485 , published online 18 February; see the Perspective by Haque and Nelson ) present a strategy to explore the refraction and absorption properties of a group of cyanine dyes for designing materials that have properties corresponding to technologically interesting telecommunications windows. The optical properties of the cyanine molecule was controlled by adding heavy chalcogen atoms (selenium) into the end groups of the molecular structure. While producing a series of molecules meeting criteria for feasible application, the work also demonstrates a route to improve the performance of nonlinear optical materials.Keywords
This publication has 26 references indexed in Scilit:
- All-optical high-speed signal processing with silicon–organic hybrid slot waveguidesNature Photonics, 2009
- Ultralarge and Thermally Stable Electro-Optic Activities from Supramolecular Self-Assembled Molecular GlassesJournal of the American Chemical Society, 2007
- Terahertz all-optical modulation in a silicon–polymer hybrid systemNature Materials, 2006
- Bisdioxaborine Polymethines with Large Third-Order Nonlinearities for All-Optical Signal ProcessingJournal of the American Chemical Society, 2006
- Nonlinear refraction and multiphoton absorption in polydiacetylenes from 1200 to 2200 nmPhysical Review B, 2004
- Structure−Property Relationships for Two-Photon Absorbing Chromophores: Bis-Donor Diphenylpolyene and Bis(styryl)benzene DerivativesJournal of the American Chemical Society, 2000
- Electric Field Modulated Nonlinear Optical Properties of Donor-Acceptor Polyenes: Sum-Over-States Investigation of the Relationship between Molecular Polarizabilities (.alpha., .beta., and .gamma.) and Bond Length AlternationJournal of the American Chemical Society, 1994
- Third-Order Nonlinear Optical Response in Organic Materials: Theoretical and Experimental AspectsChemical Reviews, 1994
- Relation Between Bond-Length Alternation and Second Electronic Hyperpolarizability of Conjugated Organic MoleculesScience, 1993
- Two-photon absorption as a limitation to all-optical switchingOptics Letters, 1989