Mid-Infrared Serial Microring Resonator Array for Real-Time Detection of Vapor-Phase Volatile Organic Compounds
- 1 August 2022
- journal article
- research article
- Published by American Chemical Society (ACS) in Analytical Chemistry
- Vol. 94 (31) , 11008-11015
Abstract
Chip-scale infrared spectrometers consisting of a microring resonator array (MRA) were developed for volatile organic compound (VOC) detection. The MRA is serially positioned to serve as a wavelength sorting element that enables wavelength demultiplexing. Unlike conventional devices operated by a single microring, our MRA can perform multiwavelength mid-infrared (mid-IR) sensing by routing the resonant wavelength light from a broadband mid-IR source into different sensing channels. Miniaturized spectrometer devices were fabricated on mid-IR transparent silicon-rich silicon nitride (SiNx) thin films through complementary metal-oxide-semiconductor (CMOS) processes, thus enabling wafer-level manufacturing and packaging. The spectral distribution of the resonance lines and the optimization of the microring structures were designed using finite-difference time-domain (FDTD) modeling and then verified by laser spectrum scanning. Using small microring structures, the spectrum showed a large free spectral range (FSR) of 100 nm and held four spectral channels without crosstalk. Unlike near-infrared microrings using refractive index sensing, our MRA can detect hexane and ethanol vapor pulses by monitoring the intensity variation at their characteristic mid-IR absorption bands, thus providing high specificity. Applying multiwavelength detection, the sensor module can discriminate among various VOC vapors. Hence, our mid-IR MRA could be an essential component to achieve a compact spectroscopic sensing module that has the potential for applications such as remote environmental monitoring and portable health care devices.Keywords
Funding Information
- Texas A and M University
This publication has 42 references indexed in Scilit:
- Three-gas detection system with IR optical sensor based on NDIR technologyOptics and Lasers in Engineering, 2015
- High performance SOI microring resonator for biochemical sensingOptics & Laser Technology, 2014
- Heterogeneously Integrated Silicon Photonics for the Mid-Infrared and Spectroscopic SensingACS Nano, 2014
- Ultralow-loss silicon ring resonatorsOptics Letters, 2012
- A high-resolution spectrometer based on a compact planar two dimensional photonic crystal cavity arrayApplied Physics Letters, 2012
- Miniature infrared gas sensors using photonic crystalsJournal of Applied Physics, 2011
- Silicon waveguides and ring resonators at 5.5 μmApplied Physics Letters, 2010
- Single virus detection from the reactive shift of a whispering-gallery modeProceedings of the National Academy of Sciences, 2008
- Whispering-gallery-mode biosensing: label-free detection down to single moleculesNature Methods, 2008
- Silicon microring resonators with 1.5-μm radiusOptics Express, 2008