Heteroatom oxidation controls singlet–triplet energy splitting in singlet fission building blocks
Open Access
- 24 December 2021
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 58 (9) , 1338-1341
Abstract
N - and S -heteroatom oxidation is shown to induce appropriate energy splitting between the first singlet and triplet excited states in conjugated building blocks, making singlet fission thermodynamically possible.Keywords
Funding Information
- H2020 Marie Skłodowska-Curie Actions (836849)
This publication has 26 references indexed in Scilit:
- New Thiadiazole Dioxide Bridging Ligand with a Stable Radical Form for the Construction of Magnetic Coordination ChainsCrystal Growth & Design, 2014
- Reactions of vicinal nitroamines with sulfur monochloride—a short and convenient route to fused 1,2,5-thiadiazoles and their N-oxidesTetrahedron Letters, 2013
- Hot exciton dissociation in polymer solar cellsNature Materials, 2012
- Singlet FissionChemical Reviews, 2010
- Synthesis of π-Extended Thiadiazole (Oxides) and Their Electronic PropertiesOrganic Letters, 2010
- Do [all]-S,S′-Dioxide Oligothiophenes Show Electronic and Optical Properties of Oligoenes and/or of Oligothiophenes?Journal of the American Chemical Society, 2010
- Singlet Fission for Dye-Sensitized Solar Cells: Can a Suitable Sensitizer Be Found?Journal of the American Chemical Society, 2006
- Easy access to the family of thiazole N-oxides using HOF·CH 3 CNChemical Communications, 2006
- Bimolecular radiationless transitions in crystalline tetraceneChemical Physics Letters, 1968
- Double-Photon Excitation of Fluorescence in Anthracene Single CrystalsThe Journal of Chemical Physics, 1963