ELECTRONIC STATES OF HYDRATED VANADIUM (II) ION
Authors:
- Ruth M. BennettRBRuth M. Bennett
- O. G. HolmesOHO. G. Holmes
- 1 December 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (12) , 2319-2323
Abstract
The optical absorption of a single crystal of VSO4.7H2O was measured in the range 9000–35,000 cm−1. The three observed bands were assigned to transitions between the four orbital levels resulting from cubic electrostatic perturbation of the spherical terms of configuration 3d3. Values of Dq = 1200 cm−1 and E = 10,000 cm−1 were derived from the spectral analysis.Keywords
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