Resonance Raman observation of the FeIVO stretching vibration in models for the active site of horse radish peroxidase compound II

Authors:
  • MSM. Schappacher
    M. Schappacher
  • GCG. Chottard
    G. Chottard
  • RWR. Weiss
    R. Weiss
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Abstract
The tetrahydrofuran and 1-methylimidazole adducts of ferryl (FeIV O)‘picket fence’ porphyrin, a model for horse radish peroxidase compound II, exhibit FeIV O vibrations, located at 829 and 807 cm–1 as shown by resonance Raman spectroscopy.
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