The Metal‐Catalyzed Cyclotrimerization of Ferrocenylethyne – Preparation and Characterization of 1,2,4‐Triferrocenylbenzene
- 14 March 2006
- journal article
- research article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 2006 (7) , 1726-1732
Abstract
1,2,4‐Triferrocenylbenzene was isolated and fully characterized for the first time. It was obtained, together with 1,3,5‐triferrocenylbenzene, by cyclotrimerization reaction, catalyzed either by metalloporphyrins or cobaltocene. The latter catalyst gave better results. The isomerically different triferrocenylbenzenes exhibit different properties. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)Keywords
This publication has 54 references indexed in Scilit:
- EditorialGenes to Cells, 2005
- Comparison of AB2 and AB4 monomers in ferrocene-cored benzyl ether dendrimersTetrahedron, 2005
- Binding Control and Stoichiometry of Ferrocenyl Dendrimers at a Molecular PrintboardJournal of the American Chemical Society, 2004
- Organoiron polymersCoordination Chemistry Reviews, 2003
- Modulation of the Communication between Redox Centers in a Tris(ferrocene)‐tren Ligand by Complexation of Lanthanide IonsEuropean Journal of Inorganic Chemistry, 2003
- A ferrocene dendrimer based on a cyclotriphosphazene coreTetrahedron Letters, 2003
- Ferrocenyl Dendrimers Incorporated into Mesoporous Silica: New Hybrid Redox-Active MaterialsChemistry of Materials, 2003
- Dendrimers and Dendrons2001
- Mixed Ferrocene-Cobaltocenium Dendrimers: The Most Stable Organometallic Redox Systems Combined in a Dendritic MoleculeAngewandte Chemie International Edition, 2000
- CONVERSION OF METHYL KETONES INTO TERMINAL ACETYLENES: ETHYNYLFERROCENEOrganic Syntheses, 1996