In situ investigation of the mechanochemically promoted Pd–Ce interaction under stoichiometric methane oxidation conditions
Open Access
- 8 December 2022
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in EES Catalysis
- Vol. 1 (2) , 144-152
Abstract
A stable Pd0/Pd2+ arrangement generated on Pd/CeO2 prepared by mechanochemistry enables high methane activation rates in the absence of excess oxygen being available.Keywords
Funding Information
- U.S. Department of Energy (DE-AC02-05CH11231, DE-AC02-06CH11357, DE-SC0012704)
- Marie Sklodowska-Curie Actions (897197)
- Ministerio de Ciencia e Innovación (RYC2019-026704-I, GC 2017 SGR 128, MICINN/FEDER PID2021-124572OB-C31)
This publication has 60 references indexed in Scilit:
- Low-Temperature Oxidation of MethaneScience, 2012
- Exceptional Activity for Methane Combustion over Modular Pd@CeO 2 Subunits on Functionalized Al 2 O 3Science, 2012
- The Active Phase of Palladium during Methane OxidationThe Journal of Physical Chemistry Letters, 2012
- Role of the Interface between Pd and PdO in Methane DissociationThe Journal of Physical Chemistry C, 2011
- Structure and morphology of Pd/Al2O3 and Pd/CeO2/Al2O3 combustion catalysts in Pd–PdO transformation hysteresisApplied Catalysis A: General, 2010
- Alternative fuel and gasoline in an SI engine: A comparative study of performance and emissions characteristicsFuel, 2010
- Natural gas vehicles: An option for EuropeEnergy Policy, 2010
- A versatile sample-environment cell for non-ambient X-ray scattering experimentsJournal of Applied Crystallography, 2008
- Spark ignition natural gas engines—A reviewEnergy Conversion and Management, 2007
- Electron spectroscopy of single crystal and polycrystalline cerium oxide surfacesSurface Science, 1998