Supramolecular synthesis with N-hetero-tolanes: liquid crystals and hydrogen-bonded and halogen-bonded co-crystals
- 4 December 2019
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 22 (3) , 416-419
Abstract
Different co-crystals from N-hetero-tolane derivatives are prepared by hydrogen- or halogen-bonding. Their crystal structures have been determined by single crystal X-ray diffraction (SCXRD). Highly ordered smectic liquid crystals are obtained upon protonation of compound 1 and show a remarkable thermal stability. All supramolecular aggregates, crystalline or liquid crystalline, are characterized accordingly by X-ray diffraction (XRD), polarized optical microscopy (POM), and thermal analysis (DSC).Keywords
Funding Information
- Ministerio de Economía, Industria y Competitividad, Gobierno de España (MAT2016-78465-R, CTQ2016-78557-R)
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