Mechanisms of Glass Corrosion
Authors:
- 1 July 1973
- journal article
- Published by Wiley in Journal of the American Ceramic Society
- Vol. 56 (7) , 373-377
Abstract
An approach is developed for understanding formation of gel films on glass surfaces during water exposure. Compositional and microstructural data from ir reflection spectroscopy, scanning electron microscopy, and electron microprobe analysis are used with parameters defined from solution‐analysis data to produce an SiO2 composition profile of the corroded surface. This model profile is compared with a measured profile and used to interpret differences in corrosion resistance of binary Li2O‐ and Na2O‐SiO2 glasses. Effects of corrosion temperature on surface gel structure are also discussed.Keywords
This publication has 7 references indexed in Scilit:
- New Methods for Studying Glass Corrosion KineticsApplied Spectroscopy, 1972
- The absorptiometric determination of silicon in water. Part II. Method for determining “reactive” silicon in power-station watersThe Analyst, 1963
- N° 84. — Gels de silice et verres binaires SiO2-X2O, parallélisme structural établi par spectrographie d’absorption infrarougeJournal de Chimie Physique et de Physico-Chimie Biologique, 1961
- Study of Surface Durability of Container GlassesJournal of the American Ceramic Society, 1959
- Static Fatigue of Glass. IJournal of Applied Physics, 1958
- Interference Films on Glass: II, Some Observations During Acid Leaching of X‐Ray Plate GlassJournal of the American Ceramic Society, 1953
- The Brewsterian Angle and Refractive IndicesJournal of the Optical Society of America, 1941