Synthesis of iminodi(methylphosphonic acid)-type chitosan resin and its adsorption behavior for trace metals
Authors:
- 1 January 2004
- journal article
- Published by Japan Society for Analytical Chemistry in BUNSEKI KAGAKU
- Vol. 53 (9) , 1039-1043
Abstract
A chitosan-based resin possessing the iminodi(methylphosphonic acid) moiety (IDP-type chitosan resin) was synthesized by using cross-linked chitosan as a base material. The adsorption behavior of trace metal ions on the IDP-type chitosan resin was systematically investigated using a mini-column (1 ml of the resin) packed with the resin. The concentrations of metal ions in the effluents were measured by ICP-MS and ICP-AES. The resin could adsorb four metals, such as In(III), Sn(II), Th(IV), and U(VI), by almost 100% over a wide pH range (1∼7). Uranium(VI) and thorium could not be eluted with nitric acid and hydrochloric acid (1∼6 M); other metal ions were easily and readily eluted with 1 M nitric acid. The IDP-type chitosan resin synthesized in this work can be applied to the separation of U(VI) and Th(IV) from other metal ionsKeywords
This publication has 9 references indexed in Scilit:
- Synthesis of novel chitosan resin derivatized with serine moiety for the column collection/concentration of uranium and the determination of uranium by ICP-MSAnalytica Chimica Acta, 2003
- Development of column-pretreatment chelating resins for matrix elimination/multi-element determination by inductively coupled plasma-mass spectrometryThe Analyst, 2002
- Investigation on the use of UTEVA as a stationary phase for chromatographic separation of actinides on-line to inductively coupled plasma mass spectrometryJournal of Analytical Atomic Spectrometry, 2000
- Adsorption behavior of metal ions by amidoxime chelating resinJournal of Applied Polymer Science, 2000
- Phosphonate-based resins for the selective enrichment of uranium(VI)Analytica Chimica Acta, 1999
- Determination of uranium and thorium in geological materials using extraction chromatographyThe Analyst, 1999
- Rapid separation of uranium and plutonium by extraction chromatography for determination by thermal ionisation mass spectrometryThe Analyst, 1999
- Separation and preconcentration of uranium from acidic media by extraction chromatographyAnalytica Chimica Acta, 1992
- Separation and concentration of lead, uranium and copper using polystyrene resins functionalised with azobenzylphosphonic acid ligandsThe Analyst, 1988