THE STEREOCHEMISTRY AND MASS SPECTRA OF OXOVANADIUM(IV) COMPLEXES OFN,N′-BIS(3-ETHOXYSALICYLIDENE) TRIMETHYLENEDIIMINE ANDN,N′-BIS(7-METHYLSALICYIDENE)TRIMETHYLENEDIIMINE
Authors:
- 1 February 1986
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 14 (3) , 235-240
Abstract
Oxovanadium(IV) complexes, VO[A[sbnd]C6H4ORC=N-(CH2)3-N=CROH4C6-A], (where A = 3-OC2H5, R=H and A=H, R=7-CH3) have been prepared and characterised. The studies showed that the complexes are polymeric in the solid state and exhibit distorted octahedral geometry, but break down to five-coordinate monomers in chloroform and in the gas phase.Keywords
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