NMR‐Spectroscopic Evidence of Intermediate‐Dependent Pathways for Acetic Acid Formation from Methane and Carbon Monoxide over a ZnZSM‐5 Zeolite Catalyst
- 2 March 2012
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 51 (16) , 3850-3853
Abstract
Two ways: A Zn‐modified ZSM‐5 zeolite catalyst was developed for the reaction of methane with carbon monoxide to directly produce acetic acid (see scheme) under mild conditions (573–623 K), and two different intermediate‐dependent reaction pathways were unambiguously identified for acetic acid formation by in situ solid‐state NMR spectroscopy.Keywords
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