Deactivation of HCl(v=1) and DCl(v=1) by H and D atoms at T=295 K
Authors:
- 15 February 1976
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 64 (4) , 1544-1548
Abstract
The techniques of isothermal calorimetry (for H atoms) and laser‐induced fluorescence [for HCl(1)] were combined to yield absolute rate coefficients for H and D atom removal of HCl(1) and DCl(1). At T=295 K, the rate coefficients for H+HCl(1), D+HCl(1), H+DCl(1), and D+DCl(1) are (4.6±1.4) ×1012, (6.5±2.0) ×1012, (1.1±0.3) ×1012, and (1.2±0.4) ×1012 cm3/mol⋅sec, respectively.Keywords
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