Are Mobilities in Hybrid Organic-Inorganic Halide Perovskites Actually 'High'?

Authors:
  • TBThomas M. Brenner
    Thomas M. Brenner
  • DEDavid A. Egger
    David A. Egger
  • ARAndrew M. Rappe
    Andrew M. Rappe
  • LKLeeor Kronik
    Leeor Kronik
  • GHGary Hodes
    Gary Hodes
  • DCDavid Cahen
    David Cahen
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Abstract
We present an experimental and theoretical viewpoint on the electronic carrier mobilities of typical hybrid organic-inorganic perovskites (HOIPs). While these mobilities are often quoted as high, a review of them shows that although otherwise the semiconducting properties of HOIPs are impressively good, mobilities of HOIPs used in most solar cells are actually not that high. This is especially apparent if they are compared to those of inorganic semiconductors used in other high efficiency solar cells. We critically examine possible causes and focus on electron-lattice coupling mechanisms that are active at room temperature, and can lead to carrier scattering. From this, we propose scattering due to acoustic phonons or polarons as possible causes, but also point out the difficulties with each of these in view of additional experimental and theoretical findings in the literature. Further research in this direction will contribute to making HOIP solar cells even more efficient than they already are.
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