Abstract
This review summarizes contributions made by the authors between 1990 and 2025 in the design, synthesis, and application of redox-active organometallic dendrimers and polymers. Emphasis is placed on the progressive evolution from fundamental synthetic studies to functional devices, highlighting how dendritic architectures based on ferrocene and related units have provided a rich and adaptable platform at the interface of inorganic, polymer, and materials chemistry.

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