Impacts of bitumen deposit on surface waters

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Abstract
Purpose: – This paper aims to examine the quality of the surface waters of the bitumen deposit area of Nigeria and also to establish the relationship between the deposit and the waters.Design/methodology/approach: – Physico-chemical parameters were measured using standard analytical procedures, while the elemental contents were determined using total reflection X-ray fluorescence spectroscopy. Data acquired were interpreted using statistical techniques – charts,t-test, pollution index (PI) and cross-plot analysis.Findings: – A river located close to the bitumen well contained the highest concentrations of metals that are known to be associated with hydrocarbon formation. Comparison of the levels of the analyzed parameters in the waters with their standard permissible limits showed that the levels of Cl−, SO42-, total alkalinity and Cr, Mn, Fe, Ni, Cu, Zn and Pb in the river very close to the capped bitumen well and big rivers were high and low in the small streams. This was corroborated by their pollution index values. Results of the cross-plot analysis of the waters-river close to bitumen well/bitumen (R2=0.5); small streams/bitumen (R2=0.8) and big rivers/bitumen (R2=0.2) showed moderate; strong and weak positive correlations respectively, suggesting moderate, strong and weak inter-element correlations respectively between the sets of waters and the Nigerian bitumen deposit, and also establishing relationships between the deposit and the surface waters.Originality/value: – The paper provides insight into the potability of the waters; establishment of the inter-element relationship between the bitumen deposit and the waters. These results can serve as a fingerprint for bitumen exploration elsewhere and for similar mineral deposit settings.

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