Designing Quantum Matter in Pyrochlore Iridates: A Perspective on Recent Thin-Film Advances

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Abstract
The pyrochlore iridates R 2 Ir 2 O 7 have emerged as a unique playground for exploring exotic quantum phenomena arising from the intricate interplay of strong spin-orbit coupling, electron correlations, and geometric frustration. While bulk crystals of these materials have revealed a rich landscape of correlated and topological states, recent breakthroughs in epitaxial thin-film synthesis and heterostructure engineering unlocked an entirely new dimension of discovery. This brief Perspective reviews recent advancements highlighting how new tuning knobs such as dimensional confinement, epitaxial strain, and interfacial coupling can be used to manipulate the delicate balance of competing interactions. We discuss several key discoveries enabled by this approach including the realization of the magnetic Weyl semimetal phase in (111) oriented films, strain-engineered magnetic multipolar orders, the emergence of a chiral spin liquid-like state in the quasi-2D limit, and the discovery of novel electronically anisotropic states at interfaces between pyrochlore iridates and other quantum materials, such as spin ice pyrochlores. These findings showcase that low-dimensional pyrochlore iridates provide ample opportunities for both theory and experiment to unravel, control and ultimately design novel quantum states of matter. We conclude by outlining key open questions and future directions ranging from the synthesis of new heterostructures to the application of advanced probes and the exploration of non-equilibrium phenomena.
Funding Information
  • Basic Energy Sciences (DE-SC0016371)
  • Basic Energy Sciences (DE-SC0022160)
  • National Key Research and Development Program of China (2002YFA1403400)
  • National Natural Science Foundation of China (12250710675)
  • National Natural Science Foundation of China (12434007)

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