Abstract
We report here in an efficient electrochemical oxidative selenosulfonylation of alkynes and oxysulfonylation of alkenes without use of metal catalysts. This method provides a practical access to a wide range of β‐(seleno)vinyl sulfones and β‐keto sulfones. These reactions can tolerate various functional groups and be easily scaled‐up.
Funding Information
  • National Natural Science Foundation of China (NSFC-21672035, NSFC-21804018)

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