Microscale hexagonal rods of a charge-assisted second-sphere coordination compound [Co(DABP)3][Fe(CN)6]
- 15 December 2009
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 46 (7) , 1121-1123
Abstract
A second-sphere complex [Co(DABP)3][Fe(CN)6] (1) (DABP = 5,5′-diamino-2,2′-bipyridine) is constructed from [Co(DABP)3]3+ and [Fe(CN)6]3 − through charge-assisted N–H (NH2) ⋯N(CN) hydrogen bonds; hexagonal microrods of 1 are obtained via a facile self-assembly method in the presence of surfactant.Keywords
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