Olefin epoxidation by a mono-oxygenase model. Effect of site isolation

Authors:

AMAlexander W. van der Made
Alexander W. van der Made
JSJan W. H. Smeets
Jan W. H. Smeets
RNRoeland J. M. Nolte
Roeland J. M. Nolte
WDWiendelt Drenth
Wiendelt Drenth

1 January 1983

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 21,p. 1204-1206
DOI:10.1039/c39830001204

Abstract

Anchoring of (tetraphenylporphinato)manganese(III) acetate to a rigid polymer support considerably enhances the rate of cyclohexene epoxidation by this catalyst.

Keywords

MODEL
EPOXIDATION
MONO
OLEFIN
TETRAPHENYLPORPHINATO
OXYGENASE
MANGANESE
III
CYCLOHEXENE
RIGID