High Mobility Ambipolar Diketopyrrolopyrrole‐Based Conjugated Polymer Synthesized Via Direct Arylation Polycondensation
- 29 September 2015
- journal article
- research article
- Published by Wiley in Advanced Materials
- Vol. 27 (42) , 6753-6759
Abstract
A diketopyrrolopyrrole-based conjugated polymer, PDPP-4FTVT, which exhibits ambipolar transport behavior in air with hole and electron mobilities up to 3.40 and 5.86 cm2 V−1 s−1, respectively, is synthesized via direct arylation polycondensation. Incorporation of F-atoms in β-positions of thiophene rings dramatically improves the efficiency of direct arylation polycondensation.Keywords
Funding Information
- National Natural Science Foundation of China (51333006, 21204085)
- Strategic Priority Research Program of the Chinese Academy of Sciences (XDB12010300)
This publication has 57 references indexed in Scilit:
- 25th Anniversary Article: Organic Field‐Effect Transistors: The Path Beyond Amorphous SiliconAdvanced Materials, 2014
- Record High Hole Mobility in Polymer Semiconductors via Side-Chain EngineeringJournal of the American Chemical Society, 2013
- Advances in Charge Carrier Mobilities of Semiconducting Polymers Used in Organic TransistorsChemistry of Materials, 2013
- Toward Printed Integrated Circuits based on Unipolar or Ambipolar Polymer SemiconductorsAdvanced Materials, 2013
- Solution-Processable Ambipolar Diketopyrrolopyrrole–Selenophene Polymer with Unprecedentedly High Hole and Electron MobilitiesJournal of the American Chemical Society, 2012
- Effect of Selenophene in a DPP Copolymer Incorporating a Vinyl Group for High‐Performance Organic Field‐Effect TransistorsAdvanced Materials, 2012
- A stable solution-processed polymer semiconductor with record high-mobility for printed transistorsScientific Reports, 2012
- Diketopyrrolopyrrole–Diketopyrrolopyrrole-Based Conjugated Copolymer for High-Mobility Organic Field-Effect TransistorsJournal of the American Chemical Society, 2012
- Highly π‐Extended Copolymers with Diketopyrrolopyrrole Moieties for High‐Performance Field‐Effect TransistorsAdvanced Materials, 2012
- Semiconducting polymers: the Third GenerationChemical Society Reviews, 2010