Experimental demonstration of pH-dependent electrostatic catalysis of radical reactions
Open Access
- 23 June 2015
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Science
- Vol. 6 (10) , 5623-5627
Abstract
Fluorescence spectroscopy demonstrated pH-dependent electrostatic effects on the kinetics and thermodynamics of hydrogen atom transfer between 1-hydroxy-2,2,6,6-tetramethyl-4-piperidinecarboxylic acid and {2,2,6,6-tetramethyl-4-[(7-nitro-2,1,3-benzoxadiazol-4-yl)amino]-1-piperidinyl}oxidanyl radical in dichloromethane.Keywords
Funding Information
- Australian Research Council (FT100100320, CE140100012)
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