Investigation on the Mechanism of Enhanced Formaldehyde Gas-Sensing Performance of UiO-66 by Amino Modification

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Abstract
Detection of formaldehyde is of great significance for environmental monitoring and public health. Although amino-modified MOF nanomaterials have been widely adopted to improve the gas-sensing properties for hazardous gases, the fundamental enhancement mechanism is still insufficiently clarified, especially for formaldehyde-sensing material. In this work, the adsorption enthalpies of formaldehyde on UiO-66 and UiO-66-NH2 were quantitatively extracted via MEMS variable-temperature adsorption experiments, yielding values of −21.8 and −45.9 kJ/mol, respectively. The results demonstrate that amino-modified UiO-66-NH2 enables reversible adsorption between physisorption and chemisorption, which is more favorable for gas-sensing applications. Furthermore, a formaldehyde sensor was fabricated based on a MEMS resonant microcantilever. Gas-sensing performance tests indicate that the UiO-66-NH2-based sensor displays a remarkable response to 0.5–10 ppm formaldehyde with a detection limit of 17 ppb and high selectivity. The significantly improved sensing performance experimentally validates the reasonability of the proposed mechanism. This work provides a reliable strategy for revealing the sensitivity enhancement mechanism and developing high-performance MOF-based formaldehyde sensors.
Funding Information
  • National Natural Science Foundation of China (62227815)

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