The structure of ambient water
- 10 June 2010
- journal article
- review article
- Published by Taylor & Francis in Molecular Physics
- Vol. 108 (11) , 1415-1433
Abstract
We review the spectroscopic techniques and scattering experiments used to probe the structure of water, and their interpretation using empirical and ab initio models, over the last 5 years. We show that all available scientific evidence overwhelmingly favors the view of classifying water near ambient conditions as a uniform, continuous tetrahedral liquid. While there are controversial issues in our understanding of water in the supercooled state, in confinement, at interfaces, or in solution, there is no real controversy in what is understood as regards bulk liquid water under ambient conditions.Keywords
This publication has 117 references indexed in Scilit:
- Is ambient water inhomogeneous on the nanometer-length scale?Proceedings of the National Academy of Sciences, 2010
- The inhomogeneous structure of water at ambient conditionsProceedings of the National Academy of Sciences, 2009
- Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy of liquid microjetsProceedings of the National Academy of Sciences, 2008
- Hydrogen bonding and Raman, IR, and 2D-IR spectroscopy of dilute HOD in liquid D 2 OProceedings of the National Academy of Sciences, 2007
- Tetrahedral structure or chains for liquid waterProceedings of the National Academy of Sciences, 2006
- Can simple models describe the phase diagram of water?Journal of Physics: Condensed Matter, 2005
- Local Hydration Environments of Amino Acids and Dipeptides Studied by X-ray Spectroscopy of Liquid MicrojetsThe Journal of Physical Chemistry B, 2005
- Mixture model description of the T-, P dependence of the refractive index of waterThe Journal of Chemical Physics, 2001
- Water under PressurePhysical Review Letters, 2000
- Comparison of simple potential functions for simulating liquid waterThe Journal of Chemical Physics, 1983