Asymmetric line shapes and surface enhanced infrared absorption of CO adsorbed on thin iron films on MgO(001)

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Abstract
We have measured infrared transmission spectra of CO adsorbed on in situgrownironfilms on MgO(001) under ultrahigh vacuum conditions. Even at normal incidence we observed strong absorption lines in the C–O stretch region with number, intensities, positions, and shapes dependent on CO coverage and Fe-film thickness and morphology. This absorption must be due to vibrational dipoles oblique to the substrate surface, e.g., due to molecules at island walls. The distinct absorption lines can be assigned to distinct adsorption sites on crystalline facets of epitaxial Fe islands on MgO(001). For each of the films the strongest CO line shows an asymmetric shape. Additionally, the observed absorption is enhanced by at least two orders of magnitude with respect to adiabatic intensities of, e.g., CO on NaCl. Line shapes and intensity let us suggest nonadiabatic coupling of the adsorbate vibration to electronic transitions.

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