FORMATION OF 2?-DEOXY-2-NITROADENOSINES BY REACTION OF 2?-DEOXYADENOSINES WITH COPPER(II) NITRATE/ACETIC ANHYDRIDE

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Abstract
Nitration of 9-substituted [ethyl, (Ac)2-2'-deoxyribosyl, (Ac)3-ribosyl] N6-acetyladenine derivatives with Cu(NO3)2.3H2O/Ac2O was examined. Nitration proceeded at the 2-position, although the yield was low. Removal of the acetyl groups gave 2'-deoxy-2-nitroadenosine derivatives.
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