Colloids for Catalysts: A Concept for the Preparation of Superior Catalysts of Industrial Relevance
Open Access
- 23 August 2018
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 57 (38) , 12338-12341
Abstract
Compared to conventional preparation methods for supported heterogeneous catalysts, the use of colloidal nanoparticles (NPs) allows for a precise control over size, size distribution, and distribution/location of the NPs on the support. However, common colloidal syntheses have restrictions that limit their applicability for industrial catalyst preparation. We present a simple, surfactant‐free, and scalable preparation method for colloidal NPs to overcome these restrictions. We demonstrate how precious‐metal NPs are prepared in alkaline methanol, how the particle size can be tuned, and how supported catalysts are obtained. The potential of these colloids in the preparation of improved catalysts is demonstrated by two examples from heterogeneous catalysis and electrocatalysis.Keywords
Funding Information
- H2020 Marie Skłodowska-Curie Actions (703366)
- Villum Fonden (Block Stipend)
This publication has 16 references indexed in Scilit:
- Efficient Removal of Organic Ligands from Supported Nanocrystals by Fast Thermal Annealing Enables Catalytic Studies on Well-Defined Active PhasesJournal of the American Chemical Society, 2015
- Oxide-supported Ir nanodendrites with high activity and durability for the oxygen evolution reaction in acid PEM water electrolyzersChemical Science, 2015
- Heterogene Katalysatoren – fundamental betrachtetAngewandte Chemie, 2015
- Heterogeneous CatalysisAngewandte Chemie International Edition, 2015
- BASF NanoSelect™ Technology: Innovative Supported Pd- and Pt-based Catalysts for Selective Hydrogenation ReactionsTopics in Catalysis, 2012
- Heterogeneous catalysis with supported platinum colloids: A systematic study of the interplay between support and functional ligandsJournal of Catalysis, 2011
- The Catalytic Activity of “Naked” Gold ParticlesAngewandte Chemie International Edition, 2004
- The Catalytic Activity of “Naked” Gold ParticlesAngewandte Chemie, 2004
- Flame-made platinum/alumina: structural properties and catalytic behaviour in enantioselective hydrogenationJournal of Catalysis, 2003
- Preparation of Tractable Platinum, Rhodium, and Ruthenium Nanoclusters with Small Particle Size in Organic MediaChemistry of Materials, 2000