Abstract
The catalyst-free CO2 reduction with ammonia borane in the solid state is reported. Close to 40 mmol of CO2 per gram of ammonia borane can be reduced at 0.5 MPa and 60 °C to formamide in high yield, achieving a highly atom-economical process.
Funding Information
  • Japan Society for the Promotion of Science (P21761, JP18H02032, JP19K22200, JP22H05147)
  • Ministry of Education, Culture, Sports, Science and Technology (B40G660034)

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