Chloridonitrosyl[meso-5,10,15,20-tetrakis(p-tolyl)porphyrinato-κ4N,N′,N′′,N′′′]osmium(II) tetrahydrofuran tetrasolvate
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Open Access
- 22 January 2011
- journal article
- other
- Published by International Union of Crystallography (IUCr) in Acta Crystallographica Section E Structure Reports Online
- Vol. 67 (2) , m224
Abstract
The title compound, [OsCl(NO)(C(48)H(36)N(4))]·4C(4)H(8)O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octa-hedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio.Keywords
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