EPR Spectra of [Cr(CO)2L(η-C6Me6)]+ (L = PEt3, PPh3, P(OEt)3, P(OPh)3): Analysis of Line Widths and Determination of Ground State Configuration from Interpretation of 31P Couplings
Authors:
- 1 September 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 16 (20) , 4369-4376
Abstract
No abstract availableKeywords
This publication has 21 references indexed in Scilit:
- Electronic Structure of Ligand-Bridged Complexes Containing the [Rh2]3+ Core: ESR Spectroscopy, MO Calculations, and X-ray Structures of the Three Redox Pairs [Rh2(CO)2LL'{.mu.-PhNC(Me)NPh}2]z [z = 0, 1; L = L' = PPh3, P(OPh)3; L = PPh3, L' = P(OPh)3]Inorganic Chemistry, 1994
- Structure and bonding in low-spin octahedral manganese(II) carbonyls: ligand-set control of spin delocalisationJ. Chem. Soc., Dalton Trans., 1993
- A molecular mechanics model of ligand effects. 2. Binding of phosphines to pentacarbonylchromiumInorganic Chemistry, 1992
- Combined x-ray crystallographic, single-crystal EPR, and theoretical study of metal-centered radicals of the type [.eta.5C5R5Cr(CO)2L] (R = H, Me; L = CO, tertiary phosphine)Journal of the American Chemical Society, 1991
- Electron paramagnetic resonance study of the [W(CO)4{P(OMe)3}]−radical anion trapped in a single crystal of [N(PPh3)2][W(CO)4H{P(OMe)3}]J. Chem. Soc., Dalton Trans., 1990
- E.s.r. study of the cation radical of Rh2(O2CEt)4(PPh3)2; a ? electron radicalJournal of the Chemical Society, Chemical Communications, 1979
- Reactions of tricarbonyl(η-hexamethylbenzene)chromium derivatives with nitrosonium and benzenediazonium ions: reversible oxidation versus nitrosyl- or areneazo-complex formationJ. Chem. Soc., Dalton Trans., 1975
- Crystal and molecular structures of pentacarbonyltriphenylphosphinechromium(0) and pentacarbonyl(triphenyl phosphite)chromium(0)Inorganic Chemistry, 1973
- ESR Studies of Cupric Ion in Various Oxide GlassesPhysica Status Solidi (b), 1968
- IR‐ und PMR‐Spektren von AromatenchromtricarbonylderivatenEuropean Journal of Inorganic Chemistry, 1964