Optimization of polyester sheet molding compound. Part I: Experimental study
Authors:
- 1 August 1986
- journal article
- research article
- Published by Wiley in Polymer Composites
- Vol. 7 (4) , 239-249
Abstract
A series of differential scanning calorimetry (DSC) and molding experiments were carried out to measure the effect of curing agents, namely initiators and inhibitor, on the SMC reaction. Results showed that the induction time, the reaction rate, and the limiting conversion of sheet molding compounds can be modified through the change of curing agents. The SMC resin with a higher concentration of low temperature initiator and molded at higher temperature may cure in a shorter period of time and reach a higher conversion. The shortened scorch time and shelf life can be balanced by adding small amount of inhibitor. Surface quality of molded SMC parts measured by solvent extraction process showed that limiting conversion is an important factor in SMC molding.Keywords
This publication has 12 references indexed in Scilit:
- Effect of compound composition on fast reactions of polyurethane and unsaturated polyester in the bulk statePolymer, 1985
- An experimental study on the injection molding of thermosetting polyester resinPolymer Engineering & Science, 1984
- The apparent rate constant model for kinetics of radical chain copolymerization: Chemical‐controlled processPolymer Engineering & Science, 1984
- Chemorheology of thermosetting resins. I. The chemorheology and curing kinetics of unsaturated polyester resinJournal of Applied Polymer Science, 1983
- Chemorheology of thermosetting resins. III. Effect of low‐profile additive on the chemorheology and curing kinetics of unsaturated polyester resinJournal of Applied Polymer Science, 1983
- Chemorheology of thermosetting resins. II. Effect of particulates on the chemorheology and curing kinetics of unsaturated polyester resinJournal of Applied Polymer Science, 1983
- Curing of compression molded sheet molding compoundPolymer Engineering & Science, 1981
- Curing of highly reactive polyester resin under pressure: Kinetic studies by differential scanning calorimetryJournal of Applied Polymer Science, 1975
- Calorimetric investigation of polymerization reactions. IV. Curing reaction of polyester fumarate with styreneJournal of Polymer Science Part A-1: Polymer Chemistry, 1970
- Calorimetric investigation of polymerization reactions. III. Curing reaction of epoxides with aminesJournal of Polymer Science Part A-1: Polymer Chemistry, 1970