The first synthesis of a ‘C-disaccharide’

Authors:
  • DRDominique Rouzaud
    Dominique Rouzaud
  • PSPierre Sinaÿ
    Pierre Sinaÿ
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Abstract
Condensation of 2,3,4,6-tetrabenzylglucopyranolactone with the anion of methyl 6,7-dideoxy-2,3,4-tri-O-benzyl-α-D-gluco-hept-6-ynopyranoside followed by triethylsilane reduction provided, after hydrogenolysis, the first example of a synthetic β(1 → 6′)-‘C-disaccharide.’