Designed synthesis of TS-1 crystals with controllable b-oriented length
Authors:
- 15 November 2010
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 47 (3) , 1048-1050
Abstract
TS-1 crystals with controllable b-oriented length (sheet-like morphology, TS-1-S; chain-like morphology, TS-1-C) have been rationally synthesized from addition of organic additives (urea and fluorinated surfactant of FC-4) in the starting titanosilicate gels, and catalytic and adsorptive measurements show that TS-1-S samples are very active in Beckmann rearrangement of cyclohexanone oxime, whereas TS-1-C samples are selective in adsorption for para-xylene.Keywords
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