Deoxygenative Borylation of Secondary and Tertiary Alcohols

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Abstract
Two different approaches for the deoxygenative radical borylation of secondary and tertiary alcohols are presented. These transformations either proceed through a metal‐free silyl‐radical‐mediated pathway or utilize visible‐light photoredox catalysis. Readily available xanthates or methyl oxalates are used as radical precursors. The reactions show broad substrate scope and high functional‐group tolerance, and are conducted under mild and practical conditions.
Funding Information
  • H2020 European Research Council (ERC Advanced Grant agreement No. 692640)

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