The rheology of suspensions of titanate fibers in polymer solution
Authors:
- 1 January 1977
- journal article
- research article
- Published by Wiley in Polymer Engineering & Science
- Vol. 17 (1) , 1-8
Abstract
The, Theological properties of suspensions of relatively small amounts of titanate fibers in polystyrene solution have been measured by means of a Weissenberg rheogoniometer. The titanate fibers employed have diameters smaller than 0.5 micron and aspect ratios higher than 40. It has been found that the rheological properties of the suspensions are markedly time dependent; the steady‐flow shearing stress increases with increasing time when the rate of shear is changed abruptly from an initial high value to a considerably lower final value. This behavior can be attributed to the re‐formation of a structure formed by the dispersed fibers and broken at higher shear rates. The dynamic storage modulus G′ also depends strongly upon the re‐formation of the structure. Although the structure reformation process under shear appears too complicated to be analyzed satisfactorily, an attempt has been made to generalize the experimental data with a simple equation.Keywords
This publication has 19 references indexed in Scilit:
- Rheological Properties of Disperse Systems of Spherical Particles in Polystyrene Solution at Long Time-ScalesTransactions of the Society of Rheology, 1975
- Thixotropic behavior of gel‐like systemsJournal of Applied Polymer Science, 1975
- Kinetics of structural changes in thixotropic fluidsJournal of Colloid and Interface Science, 1973
- Rheological Properties of Disperse Systems of Spherical Particles in Polystyrene Solution at Long Time ScalesJournal of the Society of Materials Science, Japan, 1973
- On the Rheopexy of Solid-Liquid Disperse SystemJournal of the Society of Materials Science, Japan, 1973
- Rheological Properties of Dispersions of Spherical Particles in Polymer SolutionsTransactions of the Society of Rheology, 1973
- Some Observations on the Flow Behavior of Clay-Water SuspensionsJournal of the Society of Materials Science, Japan, 1972
- Flow Properties of Some SuspensionsNippon kagaku zassi, 1967
- Phenomenological characterization of the rheological behaviour of inelastic reversible thixotropic and antithixotropic fluidsBritish Journal of Applied Physics, 1965
- A Property of Bessel Functions and Its Application to the Theory of Two RheometersJournal of Applied Physics, 1952