A Superhydrophobic Trifluoromethyl‐Containing Covalent Organic Framework Membrane for Efficient Oil/Water Separation

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Abstract
Oily water caused in the process of industry leads to not only the waste of resources, but also environmental pollution. Membrane separation, as a facile and efficient separation technology, has attracted widespread attention in the field of oil/water separation. The development of membrane materials with high separation performance is one of the key elements to improve separation efficiency. In this work, a superhydrophobic membrane composited with a trifluoromethyl‐containing covalent organic framework (COF) is prepared, which exhibits excellent performance on separations of oil/water mixtures and water‐in‐oil emulsions. For different composition of oil/water mixtures, the highest flux of oil is up to 32 000 L m−2 h−1 and oil/water separation efficiency is above 99%. Moreover, the high oil/water separation efficiency remains unchanged after successive cycles. This work provides a feasible scheme for the design of high‐efficiency oil/water separation membranes.
Funding Information
  • National Natural Science Foundation of China (21725404, 22101063)
  • Science and Technology Commission of Shanghai Municipality (19XD1404900)

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