Radical Copolymerization of Ferulic Acid Derivatives with Ethylenic Monomers
Authors:
- 1 January 2016
- journal article
- Published by Society of Fiber Science and Technology Japan in Journal of Fiber Science and Technology
- Vol. 72 (3) , 74-79
Abstract
Bio‐based ferulic acid (FA), (E)‐3‐(4‐hydroxy‐3‐methoxyphenyl)prop‐2‐enoic acid was converted to 1,2‐disubstituted ethylenic monomer (FA1) via methyl esterification followed by silylation with tert‐butyldimethylsilyl chloride. Radical copolymerization of FA1 with styrene (St), methyl methacrylate (MMA), and 4‐acetoxy‐3‐methoxystyrene (FA2) prepared from FA were carried out using azobisisobutyronitrile as an initiator at 80℃. It is found that FA1 was copolymerized with St and FA2, but not with MMA. The formation of copolymers was confirmed by 1H‐ and 13C‐NMR analyses. The reactivity ratios of FA1 and St estimated by the Fineman‐Ross method are rFA1=0.12 and rSt=2.46. In the case of the copolymerization of FA1 with FA2, the reactivity ratios, rFA1=0.13 and rFA2=2.66 were determined.Keywords
This publication has 19 references indexed in Scilit:
- Renewable alternating aliphatic-aromatic poly(ester-urethane)s prepared from ferulic acid and bio-based diolsEuropean Polymer Journal, 2015
- Renewable polymers derived from ferulic acid and biobased diols via ADMETEuropean Polymer Journal, 2015
- Potential applications of ferulic acid from natural sourcesBiotechnology Reports, 2014
- Recovery, concentration and purification of phenolic compounds by adsorption: A reviewJournal of Food Engineering, 2011
- Biorenewable polyethylene terephthalate mimics derived from lignin and acetic acidGreen Chemistry, 2010
- Extraction and purification of ferulic acid from flax shives, wheat and corn bran by alkaline hydrolysis and pressurised solventsFood Chemistry, 2009
- Phenolic acid profiles and antioxidant activities of wheat bran extracts and the effect of hydrolysis conditionsFood Chemistry, 2006
- Bioconversions of Ferulic Acid, an Hydroxycinnamic AcidCritical Reviews in Microbiology, 2006
- Determination of cell wall ferulic and p-coumaric acids in sugarcane bagasseAnalytica Chimica Acta, 2005
- Studies on the production of feruloyl esterase from cereal brans and sugar cane bagasse by microbial fermentationEnzyme and Microbial Technology, 2005