Catalytic Enantioselective Assembly of Homoallylic Alcohols from Dienes, Aryldiazonium Salts, and Aldehydes
- 25 February 2016
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 55 (13) , 4322-4326
Abstract
A highly selective multicomponent carbonyl allylation reaction of 1,3‐butadienes, aryldiazonium tetrafluoroborates, and aldehydes has been established under the combined catalysis of palladium acetate and chiral anion phase transfer to render the favorable assembly of chiral Z‐configured homoallylic alcohols in high yields and with excellent levels of enantioselectivity.Keywords
Funding Information
- MOST (2015CB856600)
- NSFC (21232007)
- SRG-HSC (2015SRG-HSC044)
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