PERIODATE–PERMANGANATE OXIDATIONS: I. OXIDATION OF OLEFINS
Authors:
- R. U. LemieuxRLR. U. Lemieux
- E. Von RudloffERE. Von Rudloff
- 1 November 1955
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 33 (11) , 1701-1709
Abstract
It was discovered that olefinic double bonds are readily oxidized in an aqueous solution of periodate which contains only catalytic amounts of permanganate. The data suggest that in the effective pH range of 7 to 10 the permanganate is not reduced at once beyond the manganate state and that it is regenerated from this state by periodate action. Evidence was obtained that the main course of the oxidation of an olefin of type —CH=CH— involves first permanganate oxidation to hydroxyketones which are then rapidly cleaved by periodate to products which may subsequently be oxidized by the permanganate.Keywords
This publication has 7 references indexed in Scilit:
- PERIODATE–PERMANGANATE OXIDATIONS: III. DETERMINATION OF ISOPROPYLIDENE GROUPSCanadian Journal of Chemistry, 1955
- RAPID METHOD FOR ESTIMATION OF GLYCEROL IN FERMENTATION SOLUTIONSCanadian Journal of Research, 1950
- Evidence for the dehydrogenation theory of oxidationTransactions of the Faraday Society, 1946
- Hydroxylation of Monounsaturated Fatty Materials with Hydrogen PeroxideJournal of the American Chemical Society, 1945
- Über die Hydrazide einiger Fettsäuren und über die hydrierende Wirkung des Hydrazinhydrats auf Öl‐ und LinolsäureChemische Umschau auf dem Gebiet der Fette, Oele, Wachse und Harze, 1944
- The Kinetics of the Periodate Oxidation of 1,2-GlycolsJournal of the American Chemical Society, 1938
- THE EQUILIBRIUM CONDITIONS OF THE REACTION BETWEEN MANGANATE, PERMANGANATE AND MANGANESE DIOXIDE.Journal of the American Chemical Society, 1921