Mechanism and Energetics of Silane and THF Displacement from the (η6-C6H6)Cr(CO)2(HSiEt3) and (η6-C6H6)Cr(CO)2(THF) Complexes
Authors:
- 8 February 2005
- journal article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 24 (6) , 1156-1160
Abstract
No abstract availableThis publication has 22 references indexed in Scilit:
- Investigation into the reactivity of M(η5-C5R5)(CO)2(alkane) (M = Mn or Re; R = H, Me or Ph; alkane = n-heptane or cyclopentane) and Re(η5-C5H5)(CO)2(Xe) in solution at cryogenic and room temperatureJ. Chem. Soc., Dalton Trans., 2000
- An Unusual Solvent Isotope Effect in the Reaction of W(CO)5(solv) (solv = Cyclohexane or Cyclohexane-d12) with THFOrganometallics, 2000
- Transition Metal Alkane Complexes†Chemical Reviews, 1996
- Characterization of the energy surface for the oxidative addition of silanes to manganese complex CpMn(CO)2(heptane)Journal of the American Chemical Society, 1992
- Flash-photolysis studies of the photochemical reactions of silanes with chromium hexacarbonylJournal of the American Chemical Society, 1991
- Thermochemistry of silane substitution of CO in metal carbonyl complexes. Interaction of silanes with metal centersJournal of the American Chemical Society, 1990
- Organometallic chemistry in supercritical fluids. The generation and detection of dinitrogen and nonclassical dihydrogen complexes of Group 6, 7, and 8 transition metals at room temperatureJournal of the American Chemical Society, 1990
- η2 Coordination of Si–H σ Bonds to Transition Metals1990
- Oxidative addition of trisubstituted silanes to photochemically generated coordinatively unsaturated species (.eta.4-C4H4)Fe(CO)2, (.eta.5-C5H5)Mn(CO)2, and (.eta.6-C6H6)Cr(CO)2 and related moleculesOrganometallics, 1987
- Hydrido silyl complexes. 9. Chromium-hydrogen-silicon three-center bonding in C6Me6(CO)2Cr(H)SiHPh2Organometallics, 1987