Hydrogen generation from a sodium borohydride–nickel core@shell structure under hydrolytic conditions
Open Access
- 12 June 2019
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Nanoscale Advances
- Vol. 1 (7) , 2707-2717
Abstract
Sodium borohydride (NaBH4) is an attractive hydrogen carrier owing to its reactivity with water: it can generate 4 equivalents of H2by hydrolysis (NaBH4+ 4H2O → NaB(OH)4+ 4H2).Keywords
Funding Information
- Agence Nationale de la Recherche (ANR-16-CE05-0009)
- Office of Naval Research Global (N62909-16-1-2155)
- Australian Research Council
This publication has 46 references indexed in Scilit:
- Hydrogen from sodium borohydride and fossil source: An energetic and economical comparisonInternational Journal of Hydrogen Energy, 2012
- Kinetics of hydrolysis of sodium borohydride for hydrogen production in fuel cell applications: A reviewInternational Journal of Hydrogen Energy, 2011
- Hydrogen generation from aqueous acid-catalyzed hydrolysis of sodium borohydrideInternational Journal of Hydrogen Energy, 2010
- Sodium Borohydride Hydrolysis as Hydrogen Generator: Issues, State of the Art and Applicability Upstream from a Fuel CellFuel Cells, 2010
- Hydrogen generation from solid NaBH4 with catalytic solution for planar air-breathing proton exchange membrane fuel cellsInternational Journal of Hydrogen Energy, 2010
- Cu2+-induced room temperature hydrogen release from ammonia boraneEnergy & Environmental Science, 2009
- Hydrogen generation by hydrolysis of NaBH4 with efficient Co–P–B catalyst: A kinetic studyJournal of Power Sources, 2009
- Minimizing water utilization in hydrolysis of sodium borohydride: The role of sodium metaborate hydratesInternational Journal of Hydrogen Energy, 2007
- Borohydride Reduction of Nickel and Copper Ions in Aqueous and Nonaqueous Media. Controllable Chemistry Leading to Nanoscale Metal and Metal Boride ParticlesLangmuir, 1994
- Sodium Borohydride, Its Hydrolysis and its Use as a Reducing Agent and in the Generation of Hydrogen1Journal of the American Chemical Society, 1953