Physiochemical Characterization of Biochars from Six Feedstocks and Their Effects on the Sorption of Atrazine in an Organic Soil

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Abstract
Application of biochars in agricultural soils has the potential to reduce groundwater contamination of atrazine, a widely used herbicide in the US, therefore sustaining environmental quality and reducing human health issues. This study was conducted to characterize biochars produced from six feedstocks and investigate their ability to remove and retain atrazine in an organic-rich soil. Australian pine (AP), Brazilian pepper (BP), coconut husk (CH), cypress (Cy), loblolly pine (L), and pecan shell (P) feedstocks were pyrolyzed at 350 °C and 500 °C. Adsorption and desorption behaviors of atrazine were explained using Freundlich isotherms. Higher pyrolysis temperature increased specific surface area (5 times), total pore volume (2.5 times), and aromaticity (1.4 times) of the biochars. CH feedstock produced the most effective biochars (CH350 and CH500), which adsorb 8–12% more atrazine than unamended soils. CH350 biochar performed the best (Kd ads = 13.80, KOC = 153.63, Kd des = 16.98) and had significantly higher (p < 0.05) adsorption than unamended soil, possibly resulting from its highest cation exchange capacity (16.32 cmol kg−1). The Kd des values for atrazine desorption were greater than the Kd ads for adsorption, indicating retention of a considerable amount of atrazine by the biochar-amended soils following desorption.

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