Phenanthroline Ligands with Divergent Pyridine Units
- 1 March 2009
- journal article
- research article
- Published by SAGE Publications in Journal of Chemical Research
- Vol. 2009 (3) , 133-136
Abstract
2-Mono- and 2,9-di-substituted 1,10-phenanthrolines with 4-pyridine units attached either via 1,4-phenylene- or 4-ethynyl-phenyl spacers, have been synthesised. The strategy is based on the introduction of 4-trimethylsilylphenyl group(s) at the phenanthroline core with the subsequent ipso-substitution of TMS groups by bromine or iodine and successive Suzuki or Sonogashira reactions with 4-pyridineboronic acid or 4-ethynylpyridine, respectively.Keywords
This publication has 20 references indexed in Scilit:
- Synthesis and Self‐Assembly of a Rigid Exotopic Bisphenanthroline Macrocycle: Surface Patterning and a Supramolecular NanobasketChemistry – A European Journal, 2004
- Recent applications of the Suzuki–Miyaura cross-coupling reaction in organic synthesisTetrahedron, 2002
- Shuttles and Muscles: Linear Molecular Machines Based on Transition MetalsAccounts of Chemical Research, 2001
- Targeted chemical nucleasesAccounts of Chemical Research, 1993
- Synthesis and properties of novel ditopic polypyridine ligands bridged by one and two acetylenic bondsTetrahedron Letters, 1992
- Interlacing molecular threads on transition metals: catenands, catenates, and knotsAccounts of Chemical Research, 1990
- Concave Reagents, 5 Bimacrocyclic 1,10‐Phenanthroline CyclophanesEuropean Journal of Inorganic Chemistry, 1990
- A Synthetic Molecular Trefoil KnotAngewandte Chemie International Edition, 1989
- Nuclease activity of 1,10-phenanthroline-copper ionAccounts of Chemical Research, 1986
- Synthese de composes polyethers macrocycliques derives de la phenanthroline-1,10 diphenyl-2,9.Tetrahedron Letters, 1983